Copper-catalyzed aminooxygenation of N-allylamidines with PhI(OAc)2

A Cu-catalyzed aminoacetoxylation of N-alkenylamidines has been achieved using PhI(OAc)2 as an oxygen source for synthesis of 4-acetoxymethyl-4,5-dihydroimidazoles, which could be further converted into 2,3-diaminopropanol derivatives using AlH3 as a reductant.

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Bibliographic Details
Main Authors: Sanjaya, Stephen, Chiba, Shunsuke
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/97520
http://hdl.handle.net/10220/10632
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Institution: Nanyang Technological University
Language: English
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