2,2′-biphospholes : building blocks for tuning the HOMO-LUMO gap of π-systems using covalent bonding and metal coordination
A new angle: The insertion of a 2,2′-biphosphole subunit into π-conjugated systems offers a new way to control the HOMO–LUMO gap. Tuning of the dihedral angle (θ) between the two phosphorous heterocycles, either by metal coordination or covalent bonding through the P substitution can lead to control...
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sg-ntu-dr.10356-984202020-03-07T12:34:47Z 2,2′-biphospholes : building blocks for tuning the HOMO-LUMO gap of π-systems using covalent bonding and metal coordination Chen, Hui Delaunay, Wylliam Yu, Liujian Joly, Damien Wang, Zuoyong Li, Jin Wang, Zisu Lescop, Christophe Tondelier, Denis Geffroy, Bernard Duan, Zheng Hissler, Muriel Mathey, François Réau, Régis School of Physical and Mathematical Sciences A new angle: The insertion of a 2,2′-biphosphole subunit into π-conjugated systems offers a new way to control the HOMO–LUMO gap. Tuning of the dihedral angle (θ) between the two phosphorous heterocycles, either by metal coordination or covalent bonding through the P substitution can lead to control of the band gap. These new π-conjugated systems can be used as emitting materials in white organic light-emitting devices (WOLEDs). 2013-07-29T06:43:22Z 2019-12-06T19:55:06Z 2013-07-29T06:43:22Z 2019-12-06T19:55:06Z 2012 2012 Journal Article Chen, H., Delaunay, W., Yu, L., Joly, D., Wang, Z., Li, J., et al. (2012). 2,2′-Biphospholes: Building Blocks for Tuning the HOMO-LUMO Gap of π-Systems Using Covalent Bonding and Metal Coordination. Angewandte Chemie International Edition, 51(1), 214-217. 1433-7851 https://hdl.handle.net/10356/98420 http://hdl.handle.net/10220/12464 10.1002/anie.201105924 en Angewandte chemie international edition © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. |
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A new angle: The insertion of a 2,2′-biphosphole subunit into π-conjugated systems offers a new way to control the HOMO–LUMO gap. Tuning of the dihedral angle (θ) between the two phosphorous heterocycles, either by metal coordination or covalent bonding through the P substitution can lead to control of the band gap. These new π-conjugated systems can be used as emitting materials in white organic light-emitting devices (WOLEDs). |
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School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Chen, Hui Delaunay, Wylliam Yu, Liujian Joly, Damien Wang, Zuoyong Li, Jin Wang, Zisu Lescop, Christophe Tondelier, Denis Geffroy, Bernard Duan, Zheng Hissler, Muriel Mathey, François Réau, Régis |
| format |
Article |
| author |
Chen, Hui Delaunay, Wylliam Yu, Liujian Joly, Damien Wang, Zuoyong Li, Jin Wang, Zisu Lescop, Christophe Tondelier, Denis Geffroy, Bernard Duan, Zheng Hissler, Muriel Mathey, François Réau, Régis |
| spellingShingle |
Chen, Hui Delaunay, Wylliam Yu, Liujian Joly, Damien Wang, Zuoyong Li, Jin Wang, Zisu Lescop, Christophe Tondelier, Denis Geffroy, Bernard Duan, Zheng Hissler, Muriel Mathey, François Réau, Régis 2,2′-biphospholes : building blocks for tuning the HOMO-LUMO gap of π-systems using covalent bonding and metal coordination |
| author_sort |
Chen, Hui |
| title |
2,2′-biphospholes : building blocks for tuning the HOMO-LUMO gap of π-systems using covalent bonding and metal coordination |
| title_short |
2,2′-biphospholes : building blocks for tuning the HOMO-LUMO gap of π-systems using covalent bonding and metal coordination |
| title_full |
2,2′-biphospholes : building blocks for tuning the HOMO-LUMO gap of π-systems using covalent bonding and metal coordination |
| title_fullStr |
2,2′-biphospholes : building blocks for tuning the HOMO-LUMO gap of π-systems using covalent bonding and metal coordination |
| title_full_unstemmed |
2,2′-biphospholes : building blocks for tuning the HOMO-LUMO gap of π-systems using covalent bonding and metal coordination |
| title_sort |
2,2′-biphospholes : building blocks for tuning the homo-lumo gap of π-systems using covalent bonding and metal coordination |
| publishDate |
2013 |
| url |
https://hdl.handle.net/10356/98420 http://hdl.handle.net/10220/12464 |
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1681036335024963584 |