2,2′-biphospholes : building blocks for tuning the HOMO-LUMO gap of π-systems using covalent bonding and metal coordination
A new angle: The insertion of a 2,2′-biphosphole subunit into π-conjugated systems offers a new way to control the HOMO–LUMO gap. Tuning of the dihedral angle (θ) between the two phosphorous heterocycles, either by metal coordination or covalent bonding through the P substitution can lead to control...
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| Main Authors: | , , , , , , , , , , , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2013
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| Online Access: | https://hdl.handle.net/10356/98420 http://hdl.handle.net/10220/12464 |
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| Institution: | Nanyang Technological University |
| Language: | English |