Arene CH=O hydrogen bonding : a stereocontrolling tool in palladium-catalyzed arylation and vinylation of ketones

Arene CH=O hydrogen bonding : a stereocontrolling tool in palladium-catalyzed arylation and vinylation of ketones

Weak is powerful: For the arylation of tin enolates, the palladium catalyst engages in weak CH=O hydrogen bonds to control stereoselectivity (see scheme). Similar catalysts capable of NH=O hydrogen bonding also works well.

Saved in:
Bibliographic Details
Main Authors: Huang, Zhiyan, Lim, Li Hui, Chen, Zuliang, Li, Yongxin, Zhou, Feng, Su, Haibin, Zhou, Jianrong Steve
Other Authors: School of Materials Science & Engineering
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/99248
http://hdl.handle.net/10220/17600
Tags: Add Tag
No Tags, Be the first to tag this record!
Institution: Nanyang Technological University
Language: English
id sg-ntu-dr.10356-99248
record_format dspace
spelling sg-ntu-dr.10356-992482020-06-01T10:01:33Z Arene CH=O hydrogen bonding : a stereocontrolling tool in palladium-catalyzed arylation and vinylation of ketones Huang, Zhiyan Lim, Li Hui Chen, Zuliang Li, Yongxin Zhou, Feng Su, Haibin Zhou, Jianrong Steve School of Materials Science & Engineering School of Physical and Mathematical Sciences Weak is powerful: For the arylation of tin enolates, the palladium catalyst engages in weak CH=O hydrogen bonds to control stereoselectivity (see scheme). Similar catalysts capable of NH=O hydrogen bonding also works well. 2013-11-12T05:38:45Z 2019-12-06T20:05:02Z 2013-11-12T05:38:45Z 2019-12-06T20:05:02Z 2013 2013 Journal Article 1433-7851 https://hdl.handle.net/10356/99248 http://hdl.handle.net/10220/17600 10.1002/anie.201300621 en Angewandte chemie international edition © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
description Weak is powerful: For the arylation of tin enolates, the palladium catalyst engages in weak CH=O hydrogen bonds to control stereoselectivity (see scheme). Similar catalysts capable of NH=O hydrogen bonding also works well.
author2 School of Materials Science & Engineering
author_facet School of Materials Science & Engineering
Huang, Zhiyan
Lim, Li Hui
Chen, Zuliang
Li, Yongxin
Zhou, Feng
Su, Haibin
Zhou, Jianrong Steve
format Article
author Huang, Zhiyan
Lim, Li Hui
Chen, Zuliang
Li, Yongxin
Zhou, Feng
Su, Haibin
Zhou, Jianrong Steve
spellingShingle Huang, Zhiyan
Lim, Li Hui
Chen, Zuliang
Li, Yongxin
Zhou, Feng
Su, Haibin
Zhou, Jianrong Steve
Arene CH=O hydrogen bonding : a stereocontrolling tool in palladium-catalyzed arylation and vinylation of ketones
author_sort Huang, Zhiyan
title Arene CH=O hydrogen bonding : a stereocontrolling tool in palladium-catalyzed arylation and vinylation of ketones
title_short Arene CH=O hydrogen bonding : a stereocontrolling tool in palladium-catalyzed arylation and vinylation of ketones
title_full Arene CH=O hydrogen bonding : a stereocontrolling tool in palladium-catalyzed arylation and vinylation of ketones
title_fullStr Arene CH=O hydrogen bonding : a stereocontrolling tool in palladium-catalyzed arylation and vinylation of ketones
title_full_unstemmed Arene CH=O hydrogen bonding : a stereocontrolling tool in palladium-catalyzed arylation and vinylation of ketones
title_sort arene ch=o hydrogen bonding : a stereocontrolling tool in palladium-catalyzed arylation and vinylation of ketones
publishDate 2013
url https://hdl.handle.net/10356/99248
http://hdl.handle.net/10220/17600
_version_ 1681056991853674496

Similar Items