Arene CH=O hydrogen bonding : a stereocontrolling tool in palladium-catalyzed arylation and vinylation of ketones

• المؤلفون الرئيسيون: Huang, Zhiyan, Lim, Li Hui, Chen, Zuliang, Li, Yongxin, Zhou, Feng, Su, Haibin, Zhou, Jianrong Steve
• مؤلفون آخرون: School of Materials Science & Engineering
• التنسيق: مقال
• اللغة: English
• منشور في: 2013
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/99248; http://hdl.handle.net/10220/17600
• المؤسسة: Nanyang Technological University

Weak is powerful: For the arylation of tin enolates, the palladium catalyst engages in weak CH=O hydrogen bonds to control stereoselectivity (see scheme). Similar catalysts capable of NH=O hydrogen bonding also works well.