The insertion of terminal phosphinidene complexes into the B---H bond of amine and phosphine boranes

The insertion of terminal phosphinidene complexes into the B---H bond of amine and phosphine boranes

Push–pull complexation: Transient terminal phosphinidene complexes [RP[BOND]W(CO)5] insert at 110 °C into the B[BOND]H bonds of L[BOND]BH3 (L = Et3N, Ph3P; see scheme). The reaction is probably driven by an interaction between the nucleophilic boron and the electrophilic phosphorus.

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Main Authors: Tian, Rongqiang, Mathey, François
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/99721
http://hdl.handle.net/10220/13020
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-997212020-03-07T12:34:48Z The insertion of terminal phosphinidene complexes into the B---H bond of amine and phosphine boranes Tian, Rongqiang Mathey, François School of Physical and Mathematical Sciences Push–pull complexation: Transient terminal phosphinidene complexes [RP[BOND]W(CO)5] insert at 110 °C into the B[BOND]H bonds of L[BOND]BH3 (L = Et3N, Ph3P; see scheme). The reaction is probably driven by an interaction between the nucleophilic boron and the electrophilic phosphorus. 2013-08-05T07:08:44Z 2019-12-06T20:10:44Z 2013-08-05T07:08:44Z 2019-12-06T20:10:44Z 2012 2012 Journal Article Tian, R.,& Mathey, F. (2012). The Insertion of Terminal Phosphinidene Complexes into the B---H Bond of Amine and Phosphine Boranes. Chemistry - A European Journal, 18(36), 11210-11213. 0947-6539 https://hdl.handle.net/10356/99721 http://hdl.handle.net/10220/13020 10.1002/chem.201202277 en Chemistry - a European journal
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
description Push–pull complexation: Transient terminal phosphinidene complexes [RP[BOND]W(CO)5] insert at 110 °C into the B[BOND]H bonds of L[BOND]BH3 (L = Et3N, Ph3P; see scheme). The reaction is probably driven by an interaction between the nucleophilic boron and the electrophilic phosphorus.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Tian, Rongqiang
Mathey, François
format Article
author Tian, Rongqiang
Mathey, François
spellingShingle Tian, Rongqiang
Mathey, François
The insertion of terminal phosphinidene complexes into the B---H bond of amine and phosphine boranes
author_sort Tian, Rongqiang
title The insertion of terminal phosphinidene complexes into the B---H bond of amine and phosphine boranes
title_short The insertion of terminal phosphinidene complexes into the B---H bond of amine and phosphine boranes
title_full The insertion of terminal phosphinidene complexes into the B---H bond of amine and phosphine boranes
title_fullStr The insertion of terminal phosphinidene complexes into the B---H bond of amine and phosphine boranes
title_full_unstemmed The insertion of terminal phosphinidene complexes into the B---H bond of amine and phosphine boranes
title_sort insertion of terminal phosphinidene complexes into the b---h bond of amine and phosphine boranes
publishDate 2013
url https://hdl.handle.net/10356/99721
http://hdl.handle.net/10220/13020
_version_ 1681043055095840768

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