Redox coupled-spin crossover in cobalt β-diketonate complexes: Structural, electrochemical and computational studies

• Main Authors: Harding P., Harding D.J., Daengngern R., Thurakitsaree T., Schutte B.M., Shaw M.J., Tantirungrotechai Y.
• Format: Article
• Language: English
• Published: 2014
• Online Access: http://www.scopus.com/inward/record.url?eid=2-s2.0-84863775610&partnerID=40&md5=b7e1de9bc504e8b334b21aabe11da5da; http://cmuir.cmu.ac.th/handle/6653943832/6749
• Institution: Chiang Mai University

Structural, electrochemical, spectroelectrochemical, magnetic and spectroscopic studies are reported for the octahedral cobalt β-diketonate complexes, [Co(β-diketonate) 2(N-N)] {β-diketonate = 2,2,6,6-tetramethylheptane-3,5-dionate (tmhd); N-N = 1,10-phenanthroline (phen) 1, 2,2′-bipyridine (2,2′-bp...