Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides

We report herein Cu-catalyzed aerobic oxygenation of aliphatic C–H bonds with hydroperoxides, which proceeds by 1,5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carbon-centered radicals with molecular oxygen.

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Main Authors:	Too, Pei Chui, Tnay, Ya Lin, Chiba, Shunsuke
Other Authors:	School of Physical and Mathematical Sciences
Format:	Article
Language:	English
Published:	2014
Subjects:	DRNTU::Science::Chemistry::Organic chemistry
Online Access:	https://hdl.handle.net/10356/102607 http://hdl.handle.net/10220/19181
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Institution:	Nanyang Technological University
Language:	English

id	sg-ntu-dr.10356-102607
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spelling	sg-ntu-dr.10356-1026072023-02-28T19:23:07Z Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides Too, Pei Chui Tnay, Ya Lin Chiba, Shunsuke School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry We report herein Cu-catalyzed aerobic oxygenation of aliphatic C–H bonds with hydroperoxides, which proceeds by 1,5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carbon-centered radicals with molecular oxygen. Published version 2014-04-09T05:19:27Z 2019-12-06T20:57:30Z 2014-04-09T05:19:27Z 2019-12-06T20:57:30Z 2013 2013 Journal Article Too, P. C., Tnay, Y. L., & Chiba, S. (2013). Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides. Beilstein Journal of Organic Chemistry, 9, 1217-1225. 1860-5397 https://hdl.handle.net/10356/102607 http://hdl.handle.net/10220/19181 10.3762/bjoc.9.138 23843917 en Beilstein journal of organic chemistry © 2013 Too et al; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. application/pdf
institution	Nanyang Technological University
building	NTU Library
continent	Asia
country	Singapore Singapore
content_provider	NTU Library
collection	DR-NTU
language	English
topic	DRNTU::Science::Chemistry::Organic chemistry
spellingShingle	DRNTU::Science::Chemistry::Organic chemistry Too, Pei Chui Tnay, Ya Lin Chiba, Shunsuke Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides
description	We report herein Cu-catalyzed aerobic oxygenation of aliphatic C–H bonds with hydroperoxides, which proceeds by 1,5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carbon-centered radicals with molecular oxygen.
author2	School of Physical and Mathematical Sciences
author_facet	School of Physical and Mathematical Sciences Too, Pei Chui Tnay, Ya Lin Chiba, Shunsuke
format	Article
author	Too, Pei Chui Tnay, Ya Lin Chiba, Shunsuke
author_sort	Too, Pei Chui
title	Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides
title_short	Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides
title_full	Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides
title_fullStr	Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides
title_full_unstemmed	Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides
title_sort	copper-catalyzed aerobic aliphatic c–h oxygenation with hydroperoxides
publishDate	2014
url	https://hdl.handle.net/10356/102607 http://hdl.handle.net/10220/19181
_version_	1759853099011276800

Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides

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