Copper-catalyzed aerobic aliphatic C–H oxygenation directed by an amidine moiety

A method for the oxygenation of tertiary C–H bonds of N-alkylamidines and N-(2-alkylaryl)amidines is described that utilizes the CuBr·SMe2/2,2′-bipyridine catalytic system under an O2 atmosphere and provides dihydrooxazoles and 4H-1,3-benzoxazines. The oxygen atom is incorporated from atmospheric mo...

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Bibliographic Details
Main Authors: Wang, Yi-Feng, Chen, Hui, Zhu, Xu, Chiba, Shunsuke
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/96019
http://hdl.handle.net/10220/11278
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Institution: Nanyang Technological University
Language: English