Copper-catalyzed aerobic aliphatic C–H oxygenation directed by an amidine moiety

Copper-catalyzed aerobic aliphatic C–H oxygenation directed by an amidine moiety

A method for the oxygenation of tertiary C–H bonds of N-alkylamidines and N-(2-alkylaryl)amidines is described that utilizes the CuBr·SMe2/2,2′-bipyridine catalytic system under an O2 atmosphere and provides dihydrooxazoles and 4H-1,3-benzoxazines. The oxygen atom is incorporated from atmospheric mo...

Full description

Saved in:
Bibliographic Details
Main Authors: Wang, Yi-Feng, Chen, Hui, Zhu, Xu, Chiba, Shunsuke
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/96019
http://hdl.handle.net/10220/11278
Tags: Add Tag
No Tags, Be the first to tag this record!
Institution: Nanyang Technological University
Language: English
id sg-ntu-dr.10356-96019
record_format dspace
spelling sg-ntu-dr.10356-960192020-03-07T12:31:23Z Copper-catalyzed aerobic aliphatic C–H oxygenation directed by an amidine moiety Wang, Yi-Feng Chen, Hui Zhu, Xu Chiba, Shunsuke School of Physical and Mathematical Sciences A method for the oxygenation of tertiary C–H bonds of N-alkylamidines and N-(2-alkylaryl)amidines is described that utilizes the CuBr·SMe2/2,2′-bipyridine catalytic system under an O2 atmosphere and provides dihydrooxazoles and 4H-1,3-benzoxazines. The oxygen atom is incorporated from atmospheric molecular oxygen during the present process. 2013-07-12T03:03:59Z 2019-12-06T19:24:34Z 2013-07-12T03:03:59Z 2019-12-06T19:24:34Z 2012 2012 Journal Article Wang, Y. F., Chen, H., Zhu, X., & Chiba, S. (2012). Copper-Catalyzed Aerobic Aliphatic C–H Oxygenation Directed by an Amidine Moiety. Journal of the American Chemical Society, 134(29), 11980-11983. https://hdl.handle.net/10356/96019 http://hdl.handle.net/10220/11278 10.1021/ja305833a en Journal of the American chemical society © 2012 American Chemical Society.
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
description A method for the oxygenation of tertiary C–H bonds of N-alkylamidines and N-(2-alkylaryl)amidines is described that utilizes the CuBr·SMe2/2,2′-bipyridine catalytic system under an O2 atmosphere and provides dihydrooxazoles and 4H-1,3-benzoxazines. The oxygen atom is incorporated from atmospheric molecular oxygen during the present process.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Wang, Yi-Feng
Chen, Hui
Zhu, Xu
Chiba, Shunsuke
format Article
author Wang, Yi-Feng
Chen, Hui
Zhu, Xu
Chiba, Shunsuke
spellingShingle Wang, Yi-Feng
Chen, Hui
Zhu, Xu
Chiba, Shunsuke
Copper-catalyzed aerobic aliphatic C–H oxygenation directed by an amidine moiety
author_sort Wang, Yi-Feng
title Copper-catalyzed aerobic aliphatic C–H oxygenation directed by an amidine moiety
title_short Copper-catalyzed aerobic aliphatic C–H oxygenation directed by an amidine moiety
title_full Copper-catalyzed aerobic aliphatic C–H oxygenation directed by an amidine moiety
title_fullStr Copper-catalyzed aerobic aliphatic C–H oxygenation directed by an amidine moiety
title_full_unstemmed Copper-catalyzed aerobic aliphatic C–H oxygenation directed by an amidine moiety
title_sort copper-catalyzed aerobic aliphatic c–h oxygenation directed by an amidine moiety
publishDate 2013
url https://hdl.handle.net/10356/96019
http://hdl.handle.net/10220/11278
_version_ 1681045217218658304

Similar Items