A one-pot diastereoselective self assembly of C-stereogenic copper(I) diphosphine clusters
C-chirogenic diphosphine-based clusters with 8-membered “chairlike” Cu4Cl4L2 and 12-membered “drumlike” Cu6Cl6L3 (L = diphosphine) frameworks were prepared in one-pot syntheses from chiral diphosphines, which were generated in situ via the double hydrophosphination reaction in excellent enantio- and...
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Main Authors: | , , |
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格式: | Article |
語言: | English |
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2014
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在線閱讀: | https://hdl.handle.net/10356/103796 http://hdl.handle.net/10220/24558 |
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機構: | Nanyang Technological University |
語言: | English |