A one-pot diastereoselective self assembly of C-stereogenic copper(I) diphosphine clusters

• المؤلفون الرئيسيون: Yang, Xiang-Yuan, Li, Yongxin, Pullarkat, Sumod A.
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2014
• الموضوعات: DRNTU::Science::Chemistry::Inorganic chemistry
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/103796; http://hdl.handle.net/10220/24558

C-chirogenic diphosphine-based clusters with 8-membered “chairlike” Cu4Cl4L2 and 12-membered “drumlike” Cu6Cl6L3 (L = diphosphine) frameworks were prepared in one-pot syntheses from chiral diphosphines, which were generated in situ via the double hydrophosphination reaction in excellent enantio- and...