Formal [4+2]-annulation of vinyl azides with N-unsaturated aldimines
Highly functionalized quinolines and pyridines could be synthesized by BF3⋅OEt2-mediated reactions of vinyl azides with N-aryl and N-alkenyl aldimines, respectively. The reaction mechanism could be characterized as formal [4+2]-annulation, including unprecedented enamine-type nucleophilic attack of...
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Main Authors: | , , , |
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格式: | Article |
語言: | English |
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2014
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在線閱讀: | https://hdl.handle.net/10356/105127 http://hdl.handle.net/10220/20689 http://dx.doi.org/10.1002/asia.201402421 |
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機構: | Nanyang Technological University |
語言: | English |