A carbone-stabilized two-coordinate phosphorus(III)-centered dication

A carbone-stabilized two-coordinate phosphorus(III)-centered dication

A coordinatively unsaturated dicationic phosphorus compound has been synthesized and characterized (see structure; P pink, N blue, C gray). DFT calculations revealed that the polycation should show superior Lewis acid and σ-donor properties to the corresponding bis(dimethylamino)phosphenium cations....

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Bibliographic Details
Main Authors: Tay, Madelyn Qin Yi, Lu, Yunpeng, Ganguly, Rakesh, Vidović, Dragoslav
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/105291
http://hdl.handle.net/10220/16600
http://dx.doi.org/10.1002/anie.201209223
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Institution: Nanyang Technological University
Language: English
Description
Summary:A coordinatively unsaturated dicationic phosphorus compound has been synthesized and characterized (see structure; P pink, N blue, C gray). DFT calculations revealed that the polycation should show superior Lewis acid and σ-donor properties to the corresponding bis(dimethylamino)phosphenium cations. Preliminary investigations with PMe3 confirmed unusual reactivity patterns for the dication.

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