A carbone-stabilized two-coordinate phosphorus(III)-centered dication
A coordinatively unsaturated dicationic phosphorus compound has been synthesized and characterized (see structure; P pink, N blue, C gray). DFT calculations revealed that the polycation should show superior Lewis acid and σ-donor properties to the corresponding bis(dimethylamino)phosphenium cations....
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| Main Authors: | , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2013
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| Online Access: | https://hdl.handle.net/10356/105291 http://hdl.handle.net/10220/16600 http://dx.doi.org/10.1002/anie.201209223 |
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| Institution: | Nanyang Technological University |
| Language: | English |