Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene : electron deficiency compensation by asymmetric structural changes
The synthesis, characterization and X-ray analysis of dichloro- and dibromo-borenium cations stabilized by a 4-membered carbene are reported. The ligand's structural changes, atypical for similar systems, were caused by coordination to electron deficient fragments and its CN2P ring strain.
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Main Authors: | , , , , , |
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Other Authors: | |
Format: | Article |
Language: | English |
Published: |
2014
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/105350 http://hdl.handle.net/10220/20517 |
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Institution: | Nanyang Technological University |
Language: | English |