Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene : electron deficiency compensation by asymmetric structural changes

Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene : electron deficiency compensation by asymmetric structural changes

The synthesis, characterization and X-ray analysis of dichloro- and dibromo-borenium cations stabilized by a 4-membered carbene are reported. The ligand's structural changes, atypical for similar systems, were caused by coordination to electron deficient fragments and its CN2P ring strain.

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Bibliographic Details
Main Authors: Tay, Madelyn Qin Yi, Murugesapandian, Balasubramanian, Lu, Yunpeng, Ganguly, Rakesh, Rei, Kinjo, Vidović, Dragoslav
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2014
Subjects:
DRNTU::Science::Chemistry::Organic chemistry::Organic analysis
Online Access:https://hdl.handle.net/10356/105350
http://hdl.handle.net/10220/20517
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Institution: Nanyang Technological University
Language: English
Description
Summary:The synthesis, characterization and X-ray analysis of dichloro- and dibromo-borenium cations stabilized by a 4-membered carbene are reported. The ligand's structural changes, atypical for similar systems, were caused by coordination to electron deficient fragments and its CN2P ring strain.

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