Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene : electron deficiency compensation by asymmetric structural changes

The synthesis, characterization and X-ray analysis of dichloro- and dibromo-borenium cations stabilized by a 4-membered carbene are reported. The ligand's structural changes, atypical for similar systems, were caused by coordination to electron deficient fragments and its CN2P ring strain.

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Main Authors:	Tay, Madelyn Qin Yi, Murugesapandian, Balasubramanian, Lu, Yunpeng, Ganguly, Rakesh, Rei, Kinjo, Vidović, Dragoslav
Other Authors:	School of Physical and Mathematical Sciences
Format:	Article
Language:	English
Published:	2014
Subjects:	DRNTU::Science::Chemistry::Organic chemistry::Organic analysis
Online Access:	https://hdl.handle.net/10356/105350 http://hdl.handle.net/10220/20517
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Institution:	Nanyang Technological University
Language:	English

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spelling	sg-ntu-dr.10356-1053502023-02-28T19:35:53Z Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene : electron deficiency compensation by asymmetric structural changes Tay, Madelyn Qin Yi Murugesapandian, Balasubramanian Lu, Yunpeng Ganguly, Rakesh Rei, Kinjo Vidović, Dragoslav School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry::Organic analysis The synthesis, characterization and X-ray analysis of dichloro- and dibromo-borenium cations stabilized by a 4-membered carbene are reported. The ligand's structural changes, atypical for similar systems, were caused by coordination to electron deficient fragments and its CN2P ring strain. ASTAR (Agency for Sci., Tech. and Research, S’pore) Accepted version 2014-09-11T08:47:43Z 2019-12-06T21:49:41Z 2014-09-11T08:47:43Z 2019-12-06T21:49:41Z 2014 2014 Journal Article Tay, M. Q. Y., Murugesapandian, B., Lu, Y., Ganguly, R., Rei, K., & Vidović, D. (2014). Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene: electron deficiency compensation by asymmetric structural changes. Dalton Transactions (in press) https://hdl.handle.net/10356/105350 http://hdl.handle.net/10220/20517 10.1039/C4DT01210K en Dalton transactions © 2014 Royal Society of Chemistry. This is the author created version of a work that has been peer reviewed and accepted for publication by Dalton Transactions, Royal Society of Chemistry. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1039/C4DT01210K]. application/pdf
institution	Nanyang Technological University
building	NTU Library
continent	Asia
country	Singapore Singapore
content_provider	NTU Library
collection	DR-NTU
language	English
topic	DRNTU::Science::Chemistry::Organic chemistry::Organic analysis
spellingShingle	DRNTU::Science::Chemistry::Organic chemistry::Organic analysis Tay, Madelyn Qin Yi Murugesapandian, Balasubramanian Lu, Yunpeng Ganguly, Rakesh Rei, Kinjo Vidović, Dragoslav Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene : electron deficiency compensation by asymmetric structural changes
description	The synthesis, characterization and X-ray analysis of dichloro- and dibromo-borenium cations stabilized by a 4-membered carbene are reported. The ligand's structural changes, atypical for similar systems, were caused by coordination to electron deficient fragments and its CN2P ring strain.
author2	School of Physical and Mathematical Sciences
author_facet	School of Physical and Mathematical Sciences Tay, Madelyn Qin Yi Murugesapandian, Balasubramanian Lu, Yunpeng Ganguly, Rakesh Rei, Kinjo Vidović, Dragoslav
format	Article
author	Tay, Madelyn Qin Yi Murugesapandian, Balasubramanian Lu, Yunpeng Ganguly, Rakesh Rei, Kinjo Vidović, Dragoslav
author_sort	Tay, Madelyn Qin Yi
title	Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene : electron deficiency compensation by asymmetric structural changes
title_short	Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene : electron deficiency compensation by asymmetric structural changes
title_full	Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene : electron deficiency compensation by asymmetric structural changes
title_fullStr	Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene : electron deficiency compensation by asymmetric structural changes
title_full_unstemmed	Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene : electron deficiency compensation by asymmetric structural changes
title_sort	dihaloborenium cations stabilized by a four-membered n-heterocyclic carbene : electron deficiency compensation by asymmetric structural changes
publishDate	2014
url	https://hdl.handle.net/10356/105350 http://hdl.handle.net/10220/20517
_version_	1759857071681961984

Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene : electron deficiency compensation by asymmetric structural changes

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