A carbone-stabilized two-coordinate phosphorus(III)-centered dication

A carbone-stabilized two-coordinate phosphorus(III)-centered dication

A coordinatively unsaturated dicationic phosphorus compound has been synthesized and characterized (see structure; P pink, N blue, C gray). DFT calculations revealed that the polycation should show superior Lewis acid and σ-donor properties to the corresponding bis(dimethylamino)phosphenium cations....

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Main Authors: Tay, Madelyn Qin Yi, Lu, Yunpeng, Ganguly, Rakesh, Vidović, Dragoslav
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/105291
http://hdl.handle.net/10220/16600
http://dx.doi.org/10.1002/anie.201209223
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1052912019-12-06T21:48:49Z A carbone-stabilized two-coordinate phosphorus(III)-centered dication Tay, Madelyn Qin Yi Lu, Yunpeng Ganguly, Rakesh Vidović, Dragoslav School of Physical and Mathematical Sciences A coordinatively unsaturated dicationic phosphorus compound has been synthesized and characterized (see structure; P pink, N blue, C gray). DFT calculations revealed that the polycation should show superior Lewis acid and σ-donor properties to the corresponding bis(dimethylamino)phosphenium cations. Preliminary investigations with PMe3 confirmed unusual reactivity patterns for the dication. 2013-10-18T03:47:16Z 2019-12-06T21:48:49Z 2013-10-18T03:47:16Z 2019-12-06T21:48:49Z 2013 2013 Journal Article Tay, M. Q. Y., Lu, Y., Ganguly, R., & Vidović, D. (2013). A Carbone-Stabilized Two-Coordinate Phosphorus(III)-Centered Dication. Angewandte Chemie International Edition, 52(11), 3132-3135. 1433-7851 https://hdl.handle.net/10356/105291 http://hdl.handle.net/10220/16600 http://dx.doi.org/10.1002/anie.201209223 en Angewandte chemie international edition
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
description A coordinatively unsaturated dicationic phosphorus compound has been synthesized and characterized (see structure; P pink, N blue, C gray). DFT calculations revealed that the polycation should show superior Lewis acid and σ-donor properties to the corresponding bis(dimethylamino)phosphenium cations. Preliminary investigations with PMe3 confirmed unusual reactivity patterns for the dication.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Tay, Madelyn Qin Yi
Lu, Yunpeng
Ganguly, Rakesh
Vidović, Dragoslav
format Article
author Tay, Madelyn Qin Yi
Lu, Yunpeng
Ganguly, Rakesh
Vidović, Dragoslav
spellingShingle Tay, Madelyn Qin Yi
Lu, Yunpeng
Ganguly, Rakesh
Vidović, Dragoslav
A carbone-stabilized two-coordinate phosphorus(III)-centered dication
author_sort Tay, Madelyn Qin Yi
title A carbone-stabilized two-coordinate phosphorus(III)-centered dication
title_short A carbone-stabilized two-coordinate phosphorus(III)-centered dication
title_full A carbone-stabilized two-coordinate phosphorus(III)-centered dication
title_fullStr A carbone-stabilized two-coordinate phosphorus(III)-centered dication
title_full_unstemmed A carbone-stabilized two-coordinate phosphorus(III)-centered dication
title_sort carbone-stabilized two-coordinate phosphorus(iii)-centered dication
publishDate 2013
url https://hdl.handle.net/10356/105291
http://hdl.handle.net/10220/16600
http://dx.doi.org/10.1002/anie.201209223
_version_ 1681036210965839872

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