Weak arene C - H⋅⋅⋅O hydrogen bonding in palladium-catalyzed arylation and vinylation of lactones
Weak force in action: In the title reaction, the palladium catalyst (see figure, left) uses weak CH⋅⋅⋅O hydrogen bonding to control the absolute configuration of the new stereocenter. A similar palladium catalyst (right) used conventional NH⋅⋅⋅O hydrogen bonding to guide stereoselection.
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2013
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sg-ntu-dr.10356-1054872019-12-06T21:52:15Z Weak arene C - H⋅⋅⋅O hydrogen bonding in palladium-catalyzed arylation and vinylation of lactones Huang, Zhiyan Chen, Zuliang Lim, Li Hui Quang, Gia Chuong Phan Hirao, Hajime Zhou, Jianrong Steve School of Physical and Mathematical Sciences Weak force in action: In the title reaction, the palladium catalyst (see figure, left) uses weak CH⋅⋅⋅O hydrogen bonding to control the absolute configuration of the new stereocenter. A similar palladium catalyst (right) used conventional NH⋅⋅⋅O hydrogen bonding to guide stereoselection. 2013-10-18T02:58:15Z 2019-12-06T21:52:15Z 2013-10-18T02:58:15Z 2019-12-06T21:52:15Z 2013 2013 Journal Article Huang, Z., Chen, Z., Lim, L. H., Quang, G. C. P., Hirao, H., & Zhou, J. S. (2013). Weak arene C - H⋅⋅⋅O hydrogen bonding in palladium-catalyzed arylation and vinylation of lactones. Angewandte chemie international edition, 52(22), 5807-5812. 1433-7851 https://hdl.handle.net/10356/105487 http://hdl.handle.net/10220/16585 http://dx.doi.org/10.1002/anie.201300481 en Angewandte chemie international edition |
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Weak force in action: In the title reaction, the palladium catalyst (see figure, left) uses weak CH⋅⋅⋅O hydrogen bonding to control the absolute configuration of the new stereocenter. A similar palladium catalyst (right) used conventional NH⋅⋅⋅O hydrogen bonding to guide stereoselection. |
| author2 |
School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Huang, Zhiyan Chen, Zuliang Lim, Li Hui Quang, Gia Chuong Phan Hirao, Hajime Zhou, Jianrong Steve |
| format |
Article |
| author |
Huang, Zhiyan Chen, Zuliang Lim, Li Hui Quang, Gia Chuong Phan Hirao, Hajime Zhou, Jianrong Steve |
| spellingShingle |
Huang, Zhiyan Chen, Zuliang Lim, Li Hui Quang, Gia Chuong Phan Hirao, Hajime Zhou, Jianrong Steve Weak arene C - H⋅⋅⋅O hydrogen bonding in palladium-catalyzed arylation and vinylation of lactones |
| author_sort |
Huang, Zhiyan |
| title |
Weak arene C - H⋅⋅⋅O hydrogen bonding in palladium-catalyzed arylation and vinylation of lactones |
| title_short |
Weak arene C - H⋅⋅⋅O hydrogen bonding in palladium-catalyzed arylation and vinylation of lactones |
| title_full |
Weak arene C - H⋅⋅⋅O hydrogen bonding in palladium-catalyzed arylation and vinylation of lactones |
| title_fullStr |
Weak arene C - H⋅⋅⋅O hydrogen bonding in palladium-catalyzed arylation and vinylation of lactones |
| title_full_unstemmed |
Weak arene C - H⋅⋅⋅O hydrogen bonding in palladium-catalyzed arylation and vinylation of lactones |
| title_sort |
weak arene c - h⋅⋅⋅o hydrogen bonding in palladium-catalyzed arylation and vinylation of lactones |
| publishDate |
2013 |
| url |
https://hdl.handle.net/10356/105487 http://hdl.handle.net/10220/16585 http://dx.doi.org/10.1002/anie.201300481 |
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1681035926409576448 |