Weak arene C - H⋅⋅⋅O hydrogen bonding in palladium-catalyzed arylation and vinylation of lactones
Weak force in action: In the title reaction, the palladium catalyst (see figure, left) uses weak CH⋅⋅⋅O hydrogen bonding to control the absolute configuration of the new stereocenter. A similar palladium catalyst (right) used conventional NH⋅⋅⋅O hydrogen bonding to guide stereoselection.
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| Main Authors: | , , , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2013
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| Online Access: | https://hdl.handle.net/10356/105487 http://hdl.handle.net/10220/16585 http://dx.doi.org/10.1002/anie.201300481 |
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| Institution: | Nanyang Technological University |
| Language: | English |