Palladium-catalyzed asymmetric reductive heck reaction of aryl halides

Asymmetric reductive Heck reaction of aryl halides is realized in high stereoselectivity. Hydrogen-bond donors, trialkylammonium salts in a glycol solvent, were used to promote halide dissociation from neutral arylpalladium complexes to access cationic, stereoselective pathways.

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Main Authors:	Hirao, Hajime, Zhou, Jianrong Steve, Yue, Guizhou, Lei, Kaining
Other Authors:	School of Physical and Mathematical Sciences
Format:	Article
Language:	English
Published:	2015
Subjects:	DRNTU::Science::Physics
Online Access:	https://hdl.handle.net/10356/107339 http://hdl.handle.net/10220/25531 http://dx.doi.org/10.1002/anie.201501712
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Institution:	Nanyang Technological University
Language:	English

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spelling	sg-ntu-dr.10356-1073392019-12-06T22:29:06Z Palladium-catalyzed asymmetric reductive heck reaction of aryl halides Hirao, Hajime Zhou, Jianrong Steve Yue, Guizhou Lei, Kaining School of Physical and Mathematical Sciences DRNTU::Science::Physics Asymmetric reductive Heck reaction of aryl halides is realized in high stereoselectivity. Hydrogen-bond donors, trialkylammonium salts in a glycol solvent, were used to promote halide dissociation from neutral arylpalladium complexes to access cationic, stereoselective pathways. 2015-05-14T03:27:29Z 2019-12-06T22:29:06Z 2015-05-14T03:27:29Z 2019-12-06T22:29:06Z 2015 2015 Journal Article Yue, G., Lei, K., Hirao, H., & Zhou, J. S. (2015). Palladium-catalyzed asymmetric reductive heck reaction of aryl halides. Angewandte chemie International edition, 54(22), 6531-6535. 1433-7851 https://hdl.handle.net/10356/107339 http://hdl.handle.net/10220/25531 http://dx.doi.org/10.1002/anie.201501712 en Angewandte chemie International edition © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
institution	Nanyang Technological University
building	NTU Library
country	Singapore
collection	DR-NTU
language	English
topic	DRNTU::Science::Physics
spellingShingle	DRNTU::Science::Physics Hirao, Hajime Zhou, Jianrong Steve Yue, Guizhou Lei, Kaining Palladium-catalyzed asymmetric reductive heck reaction of aryl halides
description	Asymmetric reductive Heck reaction of aryl halides is realized in high stereoselectivity. Hydrogen-bond donors, trialkylammonium salts in a glycol solvent, were used to promote halide dissociation from neutral arylpalladium complexes to access cationic, stereoselective pathways.
author2	School of Physical and Mathematical Sciences
author_facet	School of Physical and Mathematical Sciences Hirao, Hajime Zhou, Jianrong Steve Yue, Guizhou Lei, Kaining
format	Article
author	Hirao, Hajime Zhou, Jianrong Steve Yue, Guizhou Lei, Kaining
author_sort	Hirao, Hajime
title	Palladium-catalyzed asymmetric reductive heck reaction of aryl halides
title_short	Palladium-catalyzed asymmetric reductive heck reaction of aryl halides
title_full	Palladium-catalyzed asymmetric reductive heck reaction of aryl halides
title_fullStr	Palladium-catalyzed asymmetric reductive heck reaction of aryl halides
title_full_unstemmed	Palladium-catalyzed asymmetric reductive heck reaction of aryl halides
title_sort	palladium-catalyzed asymmetric reductive heck reaction of aryl halides
publishDate	2015
url	https://hdl.handle.net/10356/107339 http://hdl.handle.net/10220/25531 http://dx.doi.org/10.1002/anie.201501712
_version_	1681044175710060544

Palladium-catalyzed asymmetric reductive heck reaction of aryl halides

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