Palladium-catalyzed asymmetric reductive heck reaction of aryl halides
Asymmetric reductive Heck reaction of aryl halides is realized in high stereoselectivity. Hydrogen-bond donors, trialkylammonium salts in a glycol solvent, were used to promote halide dissociation from neutral arylpalladium complexes to access cationic, stereoselective pathways.
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| Main Authors: | , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2015
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/107339 http://hdl.handle.net/10220/25531 http://dx.doi.org/10.1002/anie.201501712 |
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| Institution: | Nanyang Technological University |
| Language: | English |