Catalytic hydroboration of carbonyl compounds and pyridine derivatives with the NHC-parent silyliumylidene cation

Catalytic hydroboration of carbonyl compounds and pyridine derivatives with the NHC-parent silyliumylidene cation

This thesis describes the catalytic hydroboration of carbonyl compounds and pyridine derivatives mediated by an N-heterocyclic carbene-parent silyliumylidene cation to give the corresponding borate esters and N-boryl-1,4-dihydropyridine products in good yield, respectively. The catalysis also shows...

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Main Author: Lee, Jiawen
Other Authors: So Cheuk Wai
Format: Thesis-Master by Research
Language:English
Published: Nanyang Technological University 2020
Subjects:
Science::Chemistry::Inorganic chemistry::Non-metals
Science::Chemistry::Physical chemistry::Catalysis
Online Access:https://hdl.handle.net/10356/136967
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1369672023-02-28T23:59:00Z Catalytic hydroboration of carbonyl compounds and pyridine derivatives with the NHC-parent silyliumylidene cation Lee, Jiawen So Cheuk Wai School of Physical and Mathematical Sciences cwso@ntu.edu.sg Science::Chemistry::Inorganic chemistry::Non-metals Science::Chemistry::Physical chemistry::Catalysis This thesis describes the catalytic hydroboration of carbonyl compounds and pyridine derivatives mediated by an N-heterocyclic carbene-parent silyliumylidene cation to give the corresponding borate esters and N-boryl-1,4-dihydropyridine products in good yield, respectively. The catalysis also shows chemo- and regioselectivity. The mechanism was proposed and investigated by DFT calculations. Master of Science 2020-02-07T07:17:47Z 2020-02-07T07:17:47Z 2019 Thesis-Master by Research Lee, J. (2019). Catalytic hydroboration of carbonyl compounds and pyridine derivatives with the NHC-parent silyliumylidene cation. Master's thesis, Nanyang Technological University, Singapore. https://hdl.handle.net/10356/136967 10.32657/10356/136967 en This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License (CC BY-NC 4.0). application/pdf Nanyang Technological University
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Science::Chemistry::Inorganic chemistry::Non-metals
Science::Chemistry::Physical chemistry::Catalysis
spellingShingle Science::Chemistry::Inorganic chemistry::Non-metals
Science::Chemistry::Physical chemistry::Catalysis
Lee, Jiawen
Catalytic hydroboration of carbonyl compounds and pyridine derivatives with the NHC-parent silyliumylidene cation
description This thesis describes the catalytic hydroboration of carbonyl compounds and pyridine derivatives mediated by an N-heterocyclic carbene-parent silyliumylidene cation to give the corresponding borate esters and N-boryl-1,4-dihydropyridine products in good yield, respectively. The catalysis also shows chemo- and regioselectivity. The mechanism was proposed and investigated by DFT calculations.
author2 So Cheuk Wai
author_facet So Cheuk Wai
Lee, Jiawen
format Thesis-Master by Research
author Lee, Jiawen
author_sort Lee, Jiawen
title Catalytic hydroboration of carbonyl compounds and pyridine derivatives with the NHC-parent silyliumylidene cation
title_short Catalytic hydroboration of carbonyl compounds and pyridine derivatives with the NHC-parent silyliumylidene cation
title_full Catalytic hydroboration of carbonyl compounds and pyridine derivatives with the NHC-parent silyliumylidene cation
title_fullStr Catalytic hydroboration of carbonyl compounds and pyridine derivatives with the NHC-parent silyliumylidene cation
title_full_unstemmed Catalytic hydroboration of carbonyl compounds and pyridine derivatives with the NHC-parent silyliumylidene cation
title_sort catalytic hydroboration of carbonyl compounds and pyridine derivatives with the nhc-parent silyliumylidene cation
publisher Nanyang Technological University
publishDate 2020
url https://hdl.handle.net/10356/136967
_version_ 1759857924930273280

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