Catalytic hydroboration of carbonyl compounds and pyridine derivatives with the NHC-parent silyliumylidene cation
This thesis describes the catalytic hydroboration of carbonyl compounds and pyridine derivatives mediated by an N-heterocyclic carbene-parent silyliumylidene cation to give the corresponding borate esters and N-boryl-1,4-dihydropyridine products in good yield, respectively. The catalysis also shows...
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Nanyang Technological University
2020
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sg-ntu-dr.10356-1369672023-02-28T23:59:00Z Catalytic hydroboration of carbonyl compounds and pyridine derivatives with the NHC-parent silyliumylidene cation Lee, Jiawen So Cheuk Wai School of Physical and Mathematical Sciences cwso@ntu.edu.sg Science::Chemistry::Inorganic chemistry::Non-metals Science::Chemistry::Physical chemistry::Catalysis This thesis describes the catalytic hydroboration of carbonyl compounds and pyridine derivatives mediated by an N-heterocyclic carbene-parent silyliumylidene cation to give the corresponding borate esters and N-boryl-1,4-dihydropyridine products in good yield, respectively. The catalysis also shows chemo- and regioselectivity. The mechanism was proposed and investigated by DFT calculations. Master of Science 2020-02-07T07:17:47Z 2020-02-07T07:17:47Z 2019 Thesis-Master by Research Lee, J. (2019). Catalytic hydroboration of carbonyl compounds and pyridine derivatives with the NHC-parent silyliumylidene cation. Master's thesis, Nanyang Technological University, Singapore. https://hdl.handle.net/10356/136967 10.32657/10356/136967 en This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License (CC BY-NC 4.0). application/pdf Nanyang Technological University |
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Science::Chemistry::Inorganic chemistry::Non-metals Science::Chemistry::Physical chemistry::Catalysis |
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Science::Chemistry::Inorganic chemistry::Non-metals Science::Chemistry::Physical chemistry::Catalysis Lee, Jiawen Catalytic hydroboration of carbonyl compounds and pyridine derivatives with the NHC-parent silyliumylidene cation |
| description |
This thesis describes the catalytic hydroboration of carbonyl compounds and pyridine derivatives mediated by an N-heterocyclic carbene-parent silyliumylidene cation to give the corresponding borate esters and N-boryl-1,4-dihydropyridine products in good yield, respectively. The catalysis also shows chemo- and regioselectivity. The mechanism was proposed and investigated by DFT calculations. |
| author2 |
So Cheuk Wai |
| author_facet |
So Cheuk Wai Lee, Jiawen |
| format |
Thesis-Master by Research |
| author |
Lee, Jiawen |
| author_sort |
Lee, Jiawen |
| title |
Catalytic hydroboration of carbonyl compounds and pyridine derivatives with the NHC-parent silyliumylidene cation |
| title_short |
Catalytic hydroboration of carbonyl compounds and pyridine derivatives with the NHC-parent silyliumylidene cation |
| title_full |
Catalytic hydroboration of carbonyl compounds and pyridine derivatives with the NHC-parent silyliumylidene cation |
| title_fullStr |
Catalytic hydroboration of carbonyl compounds and pyridine derivatives with the NHC-parent silyliumylidene cation |
| title_full_unstemmed |
Catalytic hydroboration of carbonyl compounds and pyridine derivatives with the NHC-parent silyliumylidene cation |
| title_sort |
catalytic hydroboration of carbonyl compounds and pyridine derivatives with the nhc-parent silyliumylidene cation |
| publisher |
Nanyang Technological University |
| publishDate |
2020 |
| url |
https://hdl.handle.net/10356/136967 |
| _version_ |
1759857924930273280 |