Catalytic hydroboration of carbonyl compounds and pyridine derivatives with the NHC-parent silyliumylidene cation

• 主要作者: Lee, Jiawen
• 其他作者: So Cheuk Wai
• 格式: Thesis-Master by Research
• 語言: English
• 出版: Nanyang Technological University 2020
• 主題: Science::Chemistry::Inorganic chemistry::Non-metals; Science::Chemistry::Physical chemistry::Catalysis
• 在線閱讀: https://hdl.handle.net/10356/136967

This thesis describes the catalytic hydroboration of carbonyl compounds and pyridine derivatives mediated by an N-heterocyclic carbene-parent silyliumylidene cation to give the corresponding borate esters and N-boryl-1,4-dihydropyridine products in good yield, respectively. The catalysis also shows...