Synthesis of triphenylene-fused phosphole oxides via C-H functionalizations

• Main Authors: Md. Shafiqur Rahman, Yoshikai, Naohiko
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2021
• Subjects: Science::Chemistry; C–H Functionalization; Fluorescence
• Online Access: https://hdl.handle.net/10356/147003
• Institution: Nanyang Technological University

The synthesis of triphenylene-fused phosphole oxides has been achieved through two distinct C-H functionalization reactions as key steps. The phosphole ring was constructed by a three-component coupling of 3-(methoxymethoxy)phenylzinc chloride, an alkyne, and dichlorophenylphosphine, involving the r...