Amidinatoamidosilylene−Dibromodiborene

• المؤلفون الرئيسيون: Fan, Jun, Yang, Ming-Chung, Su, Ming-Der, So, Cheuk-Wai
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2022
• الموضوعات: Science::Chemistry; Silicon; Bromine Compounds
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/157593
• المؤسسة: Nanyang Technological University

The amidinato amidosilylene [LSiNMe2] (1, L = PhC(NtBu)2) was reacted with B2Br4(SMe2)2 in toluene at room temperature to form the bis(silylene)-tetrabromodiborane [L{Me2N}Si]2B2Br4 (2). It was then reacted with excess KC8 in THF at room temperature to afford the bis(silylene)-dibromodiborene [L{Me2...