Amidinatoamidosilylene−Dibromodiborene
The amidinato amidosilylene [LSiNMe2] (1, L = PhC(NtBu)2) was reacted with B2Br4(SMe2)2 in toluene at room temperature to form the bis(silylene)-tetrabromodiborane [L{Me2N}Si]2B2Br4 (2). It was then reacted with excess KC8 in THF at room temperature to afford the bis(silylene)-dibromodiborene [L{Me2...
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2022
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sg-ntu-dr.10356-1575932023-02-28T20:06:58Z Amidinatoamidosilylene−Dibromodiborene Fan, Jun Yang, Ming-Chung Su, Ming-Der So, Cheuk-Wai School of Physical and Mathematical Sciences Science::Chemistry Silicon Bromine Compounds The amidinato amidosilylene [LSiNMe2] (1, L = PhC(NtBu)2) was reacted with B2Br4(SMe2)2 in toluene at room temperature to form the bis(silylene)-tetrabromodiborane [L{Me2N}Si]2B2Br4 (2). It was then reacted with excess KC8 in THF at room temperature to afford the bis(silylene)-dibromodiborene [L{Me2N}Si]2B2Br2 (3). Ministry of Education (MOE) National Research Foundation (NRF) Submitted/Accepted version C.-W.S. thanks the National Research Foundation Singapore, NRF-ANR (NRF2018-NRF-ANR026 Si-POP), and Ministry of Education Singapore, AcRF Tier 2 (MOE2019-T2-2-129), for financial support. M.-C.Y. and M.-D.S. acknowledge the National Center for High-Performance Computing of Taiwan for generous amounts of computing time and the Ministry of Science and Technology of Taiwan for financial support. 2022-05-15T07:29:14Z 2022-05-15T07:29:14Z 2021 Journal Article Fan, J., Yang, M., Su, M. & So, C. (2021). Amidinatoamidosilylene−Dibromodiborene. Inorganic Chemistry, 60(21), 16065-16069. https://dx.doi.org/10.1021/acs.inorgchem.1c02541 0020-1669 https://hdl.handle.net/10356/157593 10.1021/acs.inorgchem.1c02541 21 60 16065 16069 en NRF2018-NRF-ANR026 Si-POP MOE2019-T2-2-129 Inorganic Chemistry This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.inorgchem.1c02541. application/pdf |
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Nanyang Technological University |
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Science::Chemistry Silicon Bromine Compounds |
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Science::Chemistry Silicon Bromine Compounds Fan, Jun Yang, Ming-Chung Su, Ming-Der So, Cheuk-Wai Amidinatoamidosilylene−Dibromodiborene |
| description |
The amidinato amidosilylene [LSiNMe2] (1, L = PhC(NtBu)2) was reacted with B2Br4(SMe2)2 in toluene at room temperature to form the bis(silylene)-tetrabromodiborane [L{Me2N}Si]2B2Br4 (2). It was then reacted with excess KC8 in THF at room temperature to afford the bis(silylene)-dibromodiborene [L{Me2N}Si]2B2Br2 (3). |
| author2 |
School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Fan, Jun Yang, Ming-Chung Su, Ming-Der So, Cheuk-Wai |
| format |
Article |
| author |
Fan, Jun Yang, Ming-Chung Su, Ming-Der So, Cheuk-Wai |
| author_sort |
Fan, Jun |
| title |
Amidinatoamidosilylene−Dibromodiborene |
| title_short |
Amidinatoamidosilylene−Dibromodiborene |
| title_full |
Amidinatoamidosilylene−Dibromodiborene |
| title_fullStr |
Amidinatoamidosilylene−Dibromodiborene |
| title_full_unstemmed |
Amidinatoamidosilylene−Dibromodiborene |
| title_sort |
amidinatoamidosilylene−dibromodiborene |
| publishDate |
2022 |
| url |
https://hdl.handle.net/10356/157593 |
| _version_ |
1759853050068992000 |