Amidinatoamidosilylene−Dibromodiborene

Amidinatoamidosilylene−Dibromodiborene

The amidinato amidosilylene [LSiNMe2] (1, L = PhC(NtBu)2) was reacted with B2Br4(SMe2)2 in toluene at room temperature to form the bis(silylene)-tetrabromodiborane [L{Me2N}Si]2B2Br4 (2). It was then reacted with excess KC8 in THF at room temperature to afford the bis(silylene)-dibromodiborene [L{Me2...

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Bibliographic Details
Main Authors: Fan, Jun, Yang, Ming-Chung, Su, Ming-Der, So, Cheuk-Wai
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2022
Subjects:
Science::Chemistry
Silicon
Bromine Compounds
Online Access:https://hdl.handle.net/10356/157593
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Institution: Nanyang Technological University
Language: English
Description
Summary:The amidinato amidosilylene [LSiNMe2] (1, L = PhC(NtBu)2) was reacted with B2Br4(SMe2)2 in toluene at room temperature to form the bis(silylene)-tetrabromodiborane [L{Me2N}Si]2B2Br4 (2). It was then reacted with excess KC8 in THF at room temperature to afford the bis(silylene)-dibromodiborene [L{Me2N}Si]2B2Br2 (3).

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