N-phosphinoamidinato silicon(I) and silicon(II) compounds
This thesis describes the synthesis of N-phosphinoamidinate-stabilized disilicon(I) [LSi-SiL] (L = tBu2PNC(Ph)NAr, Ar = 2,6-iPr2C6H3) 4 by the reduction of its trichlorosilane [LSiCl3, 2] and chlorosilicon(II) [LSiCl, 6] counterpart with KC8. Compounds 4 and 6 were then able to rapidly reduce CO2 to...
Saved in:
| Main Author: | |
|---|---|
| Other Authors: | |
| Format: | Thesis-Master by Research |
| Language: | English |
| Published: |
Nanyang Technological University
2023
|
| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/170104 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Institution: | Nanyang Technological University |
| Language: | English |
| Summary: | This thesis describes the synthesis of N-phosphinoamidinate-stabilized disilicon(I) [LSi-SiL] (L = tBu2PNC(Ph)NAr, Ar = 2,6-iPr2C6H3) 4 by the reduction of its trichlorosilane [LSiCl3, 2] and chlorosilicon(II) [LSiCl, 6] counterpart with KC8. Compounds 4 and 6 were then able to rapidly reduce CO2 to CO at room temperature in toluene to form 7 and 8 respectively. In addition, the chlorosilicon(II) 6 was also able to react with BI3 in toluene to afford a heterodinuclear silicon-boron complex 9. |
|---|