N-phosphinoamidinato silicon(I) and silicon(II) compounds
This thesis describes the synthesis of N-phosphinoamidinate-stabilized disilicon(I) [LSi-SiL] (L = tBu2PNC(Ph)NAr, Ar = 2,6-iPr2C6H3) 4 by the reduction of its trichlorosilane [LSiCl3, 2] and chlorosilicon(II) [LSiCl, 6] counterpart with KC8. Compounds 4 and 6 were then able to rapidly reduce CO2 to...
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Nanyang Technological University
2023
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sg-ntu-dr.10356-1701042023-09-04T07:32:08Z N-phosphinoamidinato silicon(I) and silicon(II) compounds Phang, Isabel Si Jia So Cheuk Wai School of Chemistry, Chemical Engineering and Biotechnology CWSo@ntu.edu.sg Science::Chemistry This thesis describes the synthesis of N-phosphinoamidinate-stabilized disilicon(I) [LSi-SiL] (L = tBu2PNC(Ph)NAr, Ar = 2,6-iPr2C6H3) 4 by the reduction of its trichlorosilane [LSiCl3, 2] and chlorosilicon(II) [LSiCl, 6] counterpart with KC8. Compounds 4 and 6 were then able to rapidly reduce CO2 to CO at room temperature in toluene to form 7 and 8 respectively. In addition, the chlorosilicon(II) 6 was also able to react with BI3 in toluene to afford a heterodinuclear silicon-boron complex 9. Master of Science 2023-08-28T06:10:51Z 2023-08-28T06:10:51Z 2023 Thesis-Master by Research Phang, I. S. J. (2023). N-phosphinoamidinato silicon(I) and silicon(II) compounds. Master's thesis, Nanyang Technological University, Singapore. https://hdl.handle.net/10356/170104 https://hdl.handle.net/10356/170104 10.32657/10356/170104 en This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License (CC BY-NC 4.0). application/pdf Nanyang Technological University |
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Science::Chemistry Phang, Isabel Si Jia N-phosphinoamidinato silicon(I) and silicon(II) compounds |
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This thesis describes the synthesis of N-phosphinoamidinate-stabilized disilicon(I) [LSi-SiL] (L = tBu2PNC(Ph)NAr, Ar = 2,6-iPr2C6H3) 4 by the reduction of its trichlorosilane [LSiCl3, 2] and chlorosilicon(II) [LSiCl, 6] counterpart with KC8. Compounds 4 and 6 were then able to rapidly reduce CO2 to CO at room temperature in toluene to form 7 and 8 respectively. In addition, the chlorosilicon(II) 6 was also able to react with BI3 in toluene to afford a heterodinuclear silicon-boron complex 9. |
| author2 |
So Cheuk Wai |
| author_facet |
So Cheuk Wai Phang, Isabel Si Jia |
| format |
Thesis-Master by Research |
| author |
Phang, Isabel Si Jia |
| author_sort |
Phang, Isabel Si Jia |
| title |
N-phosphinoamidinato silicon(I) and silicon(II) compounds |
| title_short |
N-phosphinoamidinato silicon(I) and silicon(II) compounds |
| title_full |
N-phosphinoamidinato silicon(I) and silicon(II) compounds |
| title_fullStr |
N-phosphinoamidinato silicon(I) and silicon(II) compounds |
| title_full_unstemmed |
N-phosphinoamidinato silicon(I) and silicon(II) compounds |
| title_sort |
n-phosphinoamidinato silicon(i) and silicon(ii) compounds |
| publisher |
Nanyang Technological University |
| publishDate |
2023 |
| url |
https://hdl.handle.net/10356/170104 |
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1779156325129781248 |