N-phosphinoamidinato silicon(I) and silicon(II) compounds
This thesis describes the synthesis of N-phosphinoamidinate-stabilized disilicon(I) [LSi-SiL] (L = tBu2PNC(Ph)NAr, Ar = 2,6-iPr2C6H3) 4 by the reduction of its trichlorosilane [LSiCl3, 2] and chlorosilicon(II) [LSiCl, 6] counterpart with KC8. Compounds 4 and 6 were then able to rapidly reduce CO2 to...
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| Format: | Thesis-Master by Research |
| Language: | English |
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Nanyang Technological University
2023
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| Online Access: | https://hdl.handle.net/10356/170104 |
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| Institution: | Nanyang Technological University |
| Language: | English |