Iron-catalyzed amidation of 1,3-dicarbonyl compounds.

• المؤلف الرئيسي: Ong, Wei Ting.
• مؤلفون آخرون: Philip Wai Hong Chan
• التنسيق: Final Year Project
• اللغة: English
• منشور في: 2010
• الموضوعات: DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
• الوصول للمادة أونلاين: http://hdl.handle.net/10356/39882

An efficient Fe-catalyzed amidation of 1,3-dicarbonyl compounds to α-amidated products through C(sp3)-H functionalization is achieved via 2 methods; indirect method of using PhI=NTs (Ts = toluene-4-sulfonyl) as nitrogen source and direct method of using PhI(OAc)2 as oxidant and TsNH2 as nitrogen sou...