Palladacycle-catalyzed asymmetric hydrophosphination of achiral heterobicyclic alkenes

• 主要作者: Ong, Yew Jin
• 其他作者: Pullarkat A. Sumod
• 格式: Final Year Project
• 語言: English
• 出版: 2018
• 主題: DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis; DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
• 在線閱讀: http://hdl.handle.net/10356/76198

Palladacycle-catalyzed asymmetric hydrophosphination of achiral heterobicyclic alkenes offers an unprecedented access towards novel chiral phosphine motifs. As an expansion of the substrate scope, four substrates that represent oxygen, nitrogen and carbon-bridged bicyclic alkenes were examined fo...