Brønsted Base-Mediated Aziridination of 2-Alkyl-Substituted-1,3-Dicarbonyl Compounds and 2-Acyl-Substituted-1,4-Dicarbonyl Compounds by Iminoiodanes

• Main Authors: Tejo, Ciputra, Tirtorahardjo, Davin, Day, David Philip, Ma, Dik-Lung, Leung, Chung-Hang, Chan, Philip Wai Hong
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2017
• Subjects: Brønsted Base-mediated; Aziridination
• Online Access: https://hdl.handle.net/10356/86641; http://hdl.handle.net/10220/44140
• Institution: Nanyang Technological University

The synthesis of α,α-diacylaziridines and α,α,β-triacylaziridines from reaction of 2-alkyl-substituted-1,3-dicarbonyl compounds and 2-acyl-substituted-1,4-dicarbonyl compounds with arylsulfonyliminoiodinanes (ArSO2N=IPh) under Brønsted base-mediated atmospheric conditions is described. The reaction...