C–H activation and nucleophilic substitution in a photochemically generated high valent iron complex

C–H activation and nucleophilic substitution in a photochemically generated high valent iron complex

The photochemical oxidation of a (TAML)FeIII complex 1 using visible light generated Ru(bpy)33+ produces valence tautomers (TAML)FeIV (1+) and (TAML˙+)FeIII (1-TAML˙+), depending on the exogenous anions. The presence of labile Cl− or Br− results in a ligand-based oxidation and stabilisation of a rad...

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Bibliographic Details
Main Authors: Lim, Jia Hui, Engelmann, Xenia, Corby, Sacha, Ganguly, Rakesh, Ray, Kallol, Soo, Han Sen
Other Authors: Interdisciplinary Graduate School (IGS)
Format: Article
Language:English
Published: 2018
Subjects:
C–H Activation
Nucleophilic
Online Access:https://hdl.handle.net/10356/87434
http://hdl.handle.net/10220/45358
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Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/87434
http://hdl.handle.net/10220/45358

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