C–H activation and nucleophilic substitution in a photochemically generated high valent iron complex

• المؤلفون الرئيسيون: Lim, Jia Hui, Engelmann, Xenia, Corby, Sacha, Ganguly, Rakesh, Ray, Kallol, Soo, Han Sen
• مؤلفون آخرون: Interdisciplinary Graduate School (IGS)
• التنسيق: مقال
• اللغة: English
• منشور في: 2018
• الموضوعات: C–H Activation; Nucleophilic
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/87434; http://hdl.handle.net/10220/45358
• المؤسسة: Nanyang Technological University

The photochemical oxidation of a (TAML)FeIII complex 1 using visible light generated Ru(bpy)33+ produces valence tautomers (TAML)FeIV (1+) and (TAML˙+)FeIII (1-TAML˙+), depending on the exogenous anions. The presence of labile Cl− or Br− results in a ligand-based oxidation and stabilisation of a rad...