C–H activation and nucleophilic substitution in a photochemically generated high valent iron complex
The photochemical oxidation of a (TAML)FeIII complex 1 using visible light generated Ru(bpy)33+ produces valence tautomers (TAML)FeIV (1+) and (TAML˙+)FeIII (1-TAML˙+), depending on the exogenous anions. The presence of labile Cl− or Br− results in a ligand-based oxidation and stabilisation of a rad...
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| Main Authors: | , , , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2018
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/87434 http://hdl.handle.net/10220/45358 |
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| Institution: | Nanyang Technological University |
| Language: | English |