Facile access to chiral ketones through metal-free oxidative C-C bond cleavage of aldehydes by O2
Giving the metal the boot: The title reaction provides facile access to functionalized chiral ketones from chiral α,α′-disubstituted aldehydes in the presence of molecular oxygen (see scheme). The CC bond-cleavage approach offers an alternative or better method relative to the typical bond-forming s...
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sg-ntu-dr.10356-946462020-03-07T12:31:30Z Facile access to chiral ketones through metal-free oxidative C-C bond cleavage of aldehydes by O2 Tiwari, Bhoopendra Zhang, Junming Chi, Robin Yonggui School of Physical and Mathematical Sciences DRNTU::Engineering::Chemical engineering::Biochemical engineering Giving the metal the boot: The title reaction provides facile access to functionalized chiral ketones from chiral α,α′-disubstituted aldehydes in the presence of molecular oxygen (see scheme). The CC bond-cleavage approach offers an alternative or better method relative to the typical bond-forming strategies used in synthesizing chiral ketones. 2012-05-22T09:02:46Z 2019-12-06T18:59:36Z 2012-05-22T09:02:46Z 2019-12-06T18:59:36Z 2012 2012 Journal Article Tiwari, B., Zhang, J. & Chi, R. Y. (2012). Facile Access to Chiral Ketones through Metal-Free Oxidative CC Bond Cleavage of Aldehydes by O2. Angewandte Chemie International Edition, 51(8), 1911-1914. https://hdl.handle.net/10356/94646 http://hdl.handle.net/10220/8117 10.1002/anie.201107473 165026 en Angewandte chemie international edition © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
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DRNTU::Engineering::Chemical engineering::Biochemical engineering Tiwari, Bhoopendra Zhang, Junming Chi, Robin Yonggui Facile access to chiral ketones through metal-free oxidative C-C bond cleavage of aldehydes by O2 |
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Giving the metal the boot: The title reaction provides facile access to functionalized chiral ketones from chiral α,α′-disubstituted aldehydes in the presence of molecular oxygen (see scheme). The CC bond-cleavage approach offers an alternative or better method relative to the typical bond-forming strategies used in synthesizing chiral ketones. |
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School of Physical and Mathematical Sciences |
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School of Physical and Mathematical Sciences Tiwari, Bhoopendra Zhang, Junming Chi, Robin Yonggui |
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Article |
author |
Tiwari, Bhoopendra Zhang, Junming Chi, Robin Yonggui |
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Tiwari, Bhoopendra |
title |
Facile access to chiral ketones through metal-free oxidative C-C bond cleavage of aldehydes by O2 |
title_short |
Facile access to chiral ketones through metal-free oxidative C-C bond cleavage of aldehydes by O2 |
title_full |
Facile access to chiral ketones through metal-free oxidative C-C bond cleavage of aldehydes by O2 |
title_fullStr |
Facile access to chiral ketones through metal-free oxidative C-C bond cleavage of aldehydes by O2 |
title_full_unstemmed |
Facile access to chiral ketones through metal-free oxidative C-C bond cleavage of aldehydes by O2 |
title_sort |
facile access to chiral ketones through metal-free oxidative c-c bond cleavage of aldehydes by o2 |
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2012 |
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https://hdl.handle.net/10356/94646 http://hdl.handle.net/10220/8117 |
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1681049420313919488 |