Facile access to chiral ketones through metal-free oxidative C-C bond cleavage of aldehydes by O2
Giving the metal the boot: The title reaction provides facile access to functionalized chiral ketones from chiral α,α′-disubstituted aldehydes in the presence of molecular oxygen (see scheme). The CC bond-cleavage approach offers an alternative or better method relative to the typical bond-forming s...
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Main Authors: | , , |
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格式: | Article |
語言: | English |
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2012
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在線閱讀: | https://hdl.handle.net/10356/94646 http://hdl.handle.net/10220/8117 |
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