N-heterocyclic carbene catalyzed C-glycosylation : a concise approach from Stetter reaction

Described herein is the first example of an organocatalytic approach for acylanion addition to the anomeric carbon of 2-nitroglucal using an N-heterocyclic carbene catalyst. Control over the reaction conditions gives β-selective and nitro-eliminated C-glycosides, providing opportunities to produce n...

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Bibliographic Details
Main Authors: Vedachalam, Seenuvasan, Tan, Shi Min, Teo, Hui Ping, Cai, Shuting, Liu, Xue-Wei
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/97333
http://hdl.handle.net/10220/10599
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Institution: Nanyang Technological University
Language: English
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