A new route to a 2-phosphanaphthalene

The reaction between methylenechlorophosphine-pentacarbonyltungsten and an isobenzofuran affords a [4 + 2] adduct whose oxygen bridge is broken by BBr3, leading to a 2-phosphanaphthalene.

Saved in:
Bibliographic Details
Main Authors: Mao, Yanli, Lim, Kelvin Meng Hui, Ganguly, Rakesh, Mathey, François
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/97453
http://hdl.handle.net/10220/10613
Tags: Add Tag
No Tags, Be the first to tag this record!
Institution: Nanyang Technological University
Language: English
Description
Summary:The reaction between methylenechlorophosphine-pentacarbonyltungsten and an isobenzofuran affords a [4 + 2] adduct whose oxygen bridge is broken by BBr3, leading to a 2-phosphanaphthalene.