Aldimine-directed branched-selective hydroarylation of styrenes

Aldimine-directed branched-selective hydroarylation of styrenes

Branching out: A simple and inexpensive cobalt/triarylphosphine catalyst promotes aldimine-directed hydroarylation of styrene with high branched regioselectivity to afford 1,1-diarylethane derivatives in good yields under mild reaction conditions. The ortho-formyl group in the hydroarylation product...

Full description

Saved in:
Bibliographic Details
Main Authors: Lee, Pin-Sheng, Yoshikai, Naohiko
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Subjects:
DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
Online Access:https://hdl.handle.net/10356/98202
http://hdl.handle.net/10220/17258
Tags: Add Tag
No Tags, Be the first to tag this record!
Institution: Nanyang Technological University
Language: English
Description
Summary:Branching out: A simple and inexpensive cobalt/triarylphosphine catalyst promotes aldimine-directed hydroarylation of styrene with high branched regioselectivity to afford 1,1-diarylethane derivatives in good yields under mild reaction conditions. The ortho-formyl group in the hydroarylation products is amenable to dehydrative cyclization, to give fused polycyclic aromatic hydrocarbons, as well as decarbonylative removal.

Similar Items