Aldimine-directed branched-selective hydroarylation of styrenes

Aldimine-directed branched-selective hydroarylation of styrenes

Branching out: A simple and inexpensive cobalt/triarylphosphine catalyst promotes aldimine-directed hydroarylation of styrene with high branched regioselectivity to afford 1,1-diarylethane derivatives in good yields under mild reaction conditions. The ortho-formyl group in the hydroarylation product...

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Main Authors: Lee, Pin-Sheng, Yoshikai, Naohiko
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Subjects:
DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
Online Access:https://hdl.handle.net/10356/98202
http://hdl.handle.net/10220/17258
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-982022020-03-07T12:34:45Z Aldimine-directed branched-selective hydroarylation of styrenes Lee, Pin-Sheng Yoshikai, Naohiko School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis Branching out: A simple and inexpensive cobalt/triarylphosphine catalyst promotes aldimine-directed hydroarylation of styrene with high branched regioselectivity to afford 1,1-diarylethane derivatives in good yields under mild reaction conditions. The ortho-formyl group in the hydroarylation products is amenable to dehydrative cyclization, to give fused polycyclic aromatic hydrocarbons, as well as decarbonylative removal. 2013-11-05T05:17:28Z 2019-12-06T19:52:02Z 2013-11-05T05:17:28Z 2019-12-06T19:52:02Z 2013 2013 Journal Article Lee, P.-S., & Yoshikai, N. (2013). Aldimine-directed branched-selective hydroarylation of styrenes. Angewandte chemie international edition, 52(4), 1240-1244. https://hdl.handle.net/10356/98202 http://hdl.handle.net/10220/17258 10.1002/anie.201207958 en Angewandte chemie international edition
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
topic DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
spellingShingle DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
Lee, Pin-Sheng
Yoshikai, Naohiko
Aldimine-directed branched-selective hydroarylation of styrenes
description Branching out: A simple and inexpensive cobalt/triarylphosphine catalyst promotes aldimine-directed hydroarylation of styrene with high branched regioselectivity to afford 1,1-diarylethane derivatives in good yields under mild reaction conditions. The ortho-formyl group in the hydroarylation products is amenable to dehydrative cyclization, to give fused polycyclic aromatic hydrocarbons, as well as decarbonylative removal.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Lee, Pin-Sheng
Yoshikai, Naohiko
format Article
author Lee, Pin-Sheng
Yoshikai, Naohiko
author_sort Lee, Pin-Sheng
title Aldimine-directed branched-selective hydroarylation of styrenes
title_short Aldimine-directed branched-selective hydroarylation of styrenes
title_full Aldimine-directed branched-selective hydroarylation of styrenes
title_fullStr Aldimine-directed branched-selective hydroarylation of styrenes
title_full_unstemmed Aldimine-directed branched-selective hydroarylation of styrenes
title_sort aldimine-directed branched-selective hydroarylation of styrenes
publishDate 2013
url https://hdl.handle.net/10356/98202
http://hdl.handle.net/10220/17258
_version_ 1681038724351131648

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