Iron-catalyzed nitrogen-directed coupling of arene and aryl bromides mediated by metallic magnesium

2-Arylpyridines, 2-alkenylpyridine, and aromatic imines can be coupled with aryl bromides in the presence of an iron catalyst, metallic magnesium, a diamine ligand and an organic dihalide oxidant at 0 °C. The use of a 1:1 mixture of tetrahydrofuran and 1,4-dioxane is essential for this CH bond activ...

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Bibliographic Details
Main Authors: Ilies, Laurean, Kobayashi, Motoaki, Matsumoto, Arimasa, Yoshikai, Naohiko, Nakamura, Eiichi
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/98283
http://hdl.handle.net/10220/12334
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Institution: Nanyang Technological University
Language: English
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