Synthesis of (±) epipentenomycin I and III

• المؤلفون الرئيسيون: Phutdhawong W., Pyne S.G., Baramee A., Buddhasukh D., Skelton B.W., White A.H.
• التنسيق: مقال
• اللغة: English
• منشور في: 2014
• الوصول للمادة أونلاين: http://www.scopus.com/inward/record.url?eid=2-s2.0-0037136170&partnerID=40&md5=7464306258441514d2a6d123050fab68; http://cmuir.cmu.ac.th/handle/6653943832/5577
• المؤسسة: Chiang Mai University

A synthesis of (±) epipentenomycin I and III is reported from a regioselective epoxidation of racemic 3-hydroxy- and 3-acetoxy-2-methylene-4-cyclopentenone, respectively, with dimethyldioxirane followed by hydrolytic ring-opening of the resulting epoxide. © 2002 Elsevier Science Ltd. All rights rese...