Synthesis of (±) epipentenomycin I and III

A synthesis of (±) epipentenomycin I and III is reported from a regioselective epoxidation of racemic 3-hydroxy- and 3-acetoxy-2-methylene-4-cyclopentenone, respectively, with dimethyldioxirane followed by hydrolytic ring-opening of the resulting epoxide. © 2002 Elsevier Science Ltd. All rights rese...

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Bibliographic Details
Main Authors: Phutdhawong W., Pyne S.G., Baramee A., Buddhasukh D., Skelton B.W., White A.H.
Format: Article
Language:English
Published: 2014
Online Access:http://www.scopus.com/inward/record.url?eid=2-s2.0-0037136170&partnerID=40&md5=7464306258441514d2a6d123050fab68
http://cmuir.cmu.ac.th/handle/6653943832/5577
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Institution: Chiang Mai University
Language: English
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Summary:A synthesis of (±) epipentenomycin I and III is reported from a regioselective epoxidation of racemic 3-hydroxy- and 3-acetoxy-2-methylene-4-cyclopentenone, respectively, with dimethyldioxirane followed by hydrolytic ring-opening of the resulting epoxide. © 2002 Elsevier Science Ltd. All rights reserved.