Changes in minority carrier lifetime of hydrogen-terminated Si surfaces in dry-and wet-air

Minority carrier lifetime of HF-treated Si (100) surfaces decreases in wet-air more rapidly than in dry-air. XPS measurements show that OH and O are mainly included in Si by keeping in wet-air and dry-air, respectively. OH cannot form network, and thus backbonded OH generates Si dangling bonds. On t...

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Bibliographic Details
Main Authors: Franco, Francisco C., Jr., Matsumoto, Taketoshi, Woo-Byoun, Kim, Kobayashi, Hikaru
Format: text
Published: Animo Repository 2012
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Online Access:https://animorepository.dlsu.edu.ph/faculty_research/5897
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Institution: De La Salle University
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Summary:Minority carrier lifetime of HF-treated Si (100) surfaces decreases in wet-air more rapidly than in dry-air. XPS measurements show that OH and O are mainly included in Si by keeping in wet-air and dry-air, respectively. OH cannot form network, and thus backbonded OH generates Si dangling bonds. On the other hand, backbonded O can form Si-O-Si networks, leading to the higher lifetime due to lower defect density. When the atmosphere is switched from dry-air to wet-air, the lifetime greatly decreases, and the workfunction increases. These changes are attributed to dominant formation of backbonded OH.