Electronic Effects in Oxidation Reactions Utilizing Dinuclear Copper Complexes with the Bis[3-(2-hydroxybenzylideneamino)phenyl] Sulfone Ligand

• Main Authors: Guidote, Armando M, Jr, Reyes, Ronald L, Kashihara, Riyo, Kurusu, Yasuhiko, Masuyama, Yoshihiro
• Format: text
• Published: Archīum Ateneo 2014
• Subjects: catalysis; copper complex; dinuclear; hydrogen peroxide; oxidation; Chemistry; Organic Chemistry
• Online Access: https://archium.ateneo.edu/chemistry-faculty-pubs/17; https://archium.ateneo.edu/cgi/viewcontent.cgi?article=1016&context=chemistry-faculty-pubs
• Institution: Ateneo De Manila University

Copper acetate and the ligands bis[3-(3-tert-butyl-2-hydroxy-5-methoxybenzylideneamino)phenyl] sulfone and bis[3-(3,5-di-tert-butyl-2-hydroxybenzylideneamino)phenyl] sulfone were reacted to form the complexes with 2:1 copper:ligand ratio, Cu2[B(t-Bu) (OMe)BAPS](µ-OCH3)2 (4) and with 2:2 copper:ligan...