Synthesis, characterization and reactivity of a series of dinuclear copper complexes bearing the ligand bis[3-(2-hydroxybenzylideneamino)phenyl] sulfone and derivatives

• Main Authors: Guidote, Armando M, Jr, Ando, Ken-ichi, Terada, Kazunori, Kurusu, Yasuhiko, Nagao, Hirotaka, Masuyama, Yoshiro
• Format: text
• Published: Archīum Ateneo 2001
• Subjects: Copper complex; Dinuclear; Schiff base type ligand; Oxidation; Catalysis; Chemistry; Organic Chemistry
• Online Access: https://archium.ateneo.edu/chemistry-faculty-pubs/51; https://www.sciencedirect.com/science/article/abs/pii/S0020169301005898
• Institution: Ateneo De Manila University

The ligands bis[3-(X-2-hydroxybenzylideneamino)phenyl] sulfones (X=none: BHBAPS, X=3-tert-butyl: BH(t-Bu)BAPS and X=3,5-dichloro: BHCl2BAPS) were prepared. These, together with Cu(OAc)2 were used in the syntheses of the dinuclear copper complexes Cu2(BBAPS)(μ-OMe)2 (1), Cu2[B(t-Bu)BAPS] (μ-OH)2 (2),...