Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride

Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride

The reaction of the tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide [(PPh2═NSiMe3)(PPh2═S)CSn:]2 (1) with AdNCO (Ad = adamantyl), ArNCO (Ar = 2,6-Pri2C6H3), and [RhCl(cod)]2 in THF afforded [(PPh2═NSiMe3)(PPh2═S)tiebar above startC{C(O)N(Ad)}tiebar above endSn:] (2), [(PPh2═NSiMe3)(PPh2═S)C¯...

Full description

Saved in:
Bibliographic Details
Main Authors: Guo, Jia-Yi, Li, Yongxin, Ganguly, Rakesh, So, Cheuk-Wai
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/100998
http://hdl.handle.net/10220/13701
Tags: Add Tag
No Tags, Be the first to tag this record!
Institution: Nanyang Technological University
Language: English
id sg-ntu-dr.10356-100998
record_format dspace
spelling sg-ntu-dr.10356-1009982020-03-07T12:34:52Z Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride Guo, Jia-Yi Li, Yongxin Ganguly, Rakesh So, Cheuk-Wai School of Physical and Mathematical Sciences The reaction of the tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide [(PPh2═NSiMe3)(PPh2═S)CSn:]2 (1) with AdNCO (Ad = adamantyl), ArNCO (Ar = 2,6-Pri2C6H3), and [RhCl(cod)]2 in THF afforded [(PPh2═NSiMe3)(PPh2═S)tiebar above startC{C(O)N(Ad)}tiebar above endSn:] (2), [(PPh2═NSiMe3)(PPh2═S)C¯{C(O)N(Ar)}Sn+:] (3), and [(PPh2═NSiMe3)(PPh2═S)C{Rh(cod)}(SnCl)] (4), respectively. Compounds 2–4 have been characterized by NMR spectroscopy and X-ray crystallography. 2013-09-25T08:05:49Z 2019-12-06T20:31:52Z 2013-09-25T08:05:49Z 2019-12-06T20:31:52Z 2012 2012 Journal Article Guo, J.-Y., Li, Y., Ganguly, R., & So, C.-K. (2012). Reactivity of a Tin(II) (Iminophosphinoyl)(thiophosphinoyl)methanediide Complex toward Isocyanates and Rhodium(I) Chloride. Organometallics, 31(10), 3888–3893. https://hdl.handle.net/10356/100998 http://hdl.handle.net/10220/13701 10.1021/om300062n en Organometallics
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
description The reaction of the tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide [(PPh2═NSiMe3)(PPh2═S)CSn:]2 (1) with AdNCO (Ad = adamantyl), ArNCO (Ar = 2,6-Pri2C6H3), and [RhCl(cod)]2 in THF afforded [(PPh2═NSiMe3)(PPh2═S)tiebar above startC{C(O)N(Ad)}tiebar above endSn:] (2), [(PPh2═NSiMe3)(PPh2═S)C¯{C(O)N(Ar)}Sn+:] (3), and [(PPh2═NSiMe3)(PPh2═S)C{Rh(cod)}(SnCl)] (4), respectively. Compounds 2–4 have been characterized by NMR spectroscopy and X-ray crystallography.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Guo, Jia-Yi
Li, Yongxin
Ganguly, Rakesh
So, Cheuk-Wai
format Article
author Guo, Jia-Yi
Li, Yongxin
Ganguly, Rakesh
So, Cheuk-Wai
spellingShingle Guo, Jia-Yi
Li, Yongxin
Ganguly, Rakesh
So, Cheuk-Wai
Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride
author_sort Guo, Jia-Yi
title Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride
title_short Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride
title_full Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride
title_fullStr Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride
title_full_unstemmed Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride
title_sort reactivity of a tin(ii) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(i) chloride
publishDate 2013
url https://hdl.handle.net/10356/100998
http://hdl.handle.net/10220/13701
_version_ 1681045574231523328

Similar Items